發(fā)布時(shí)間：2018-05-06 23:03

  本文選題：糊狀區(qū)保溫 + 顯微組織　； 參考：《昆明理工大學(xué)》2017年碩士論文

【摘要】：不銹鋼是日常生產(chǎn)生活中最常見(jiàn)的一種金屬,因其良好的力學(xué)性能和優(yōu)異的耐蝕性得到廣泛應(yīng)用。對(duì)不銹鋼進(jìn)行氮化處理,以氮代鎳,既能保證不銹鋼的各項(xiàng)性能,又能節(jié)約資源,因此受到了廣泛的關(guān)注。常見(jiàn)的不銹鋼氮化技術(shù)主要是液相滲氮和固相滲氮,但是液相滲氮存在滲氮效果較差,且工藝復(fù)雜的問(wèn)題,固相滲氮時(shí)滲氮時(shí)間長(zhǎng),且滲氮層厚度有限。本研究對(duì)滲氮工藝進(jìn)行改進(jìn),提出一種新的滲氮方法,糊狀區(qū)保溫滲氮工藝。主要是利用糊狀區(qū)溫度范圍內(nèi),固液兩相區(qū)共存的特點(diǎn),進(jìn)行一定時(shí)間的保溫,使氮?dú)庥谐浞值臅r(shí)間溶入液相,并擴(kuò)散至奧氏體相,最終提高室溫組織中的氮含量。通過(guò)實(shí)驗(yàn)及理論研究,本文最終得出以下結(jié)論:(1)糊狀區(qū)保溫過(guò)程中,氮含量隨著保溫時(shí)間的增加逐漸提高,當(dāng)?shù)獨(dú)鈮毫��?.1MPa時(shí),氮含量可從0.17%提高到0.23%,而氣孔率則從1.86%降至1.37%;當(dāng)?shù)獨(dú)鈮毫��?.4MPa時(shí),氮含量由0.29%提高到0.37%,氣孔率從1.41%降到1.06%。說(shuō)明糊狀區(qū)保溫工藝可以有效提高鋼中的氮含量,同時(shí)能夠降低鑄錠中的氣孔率。(2)探究了糊狀區(qū)保溫過(guò)程中組織隨氮含量的變化,表明在糊狀區(qū)保溫過(guò)程中,氮在鋼液中不斷溶解會(huì)使組織中的鐵素體發(fā)生等溫相變,一部分鐵素體與液相發(fā)生包晶反應(yīng)生成奧氏體,另一部分由固態(tài)相變變?yōu)閵W氏體;液相中的氮達(dá)到一定含量后,會(huì)在隨后的冷卻中直接轉(zhuǎn)變?yōu)閵W氏體。(3)闡述了糊狀區(qū)保溫增氮的機(jī)理:一方面,糊狀區(qū)增氮促使鐵素體向奧氏體轉(zhuǎn)變,奧氏體含量的增多增加了合金中氮的溶解度;另一方面,氮含量的提高促使液相直接轉(zhuǎn)變?yōu)閵W氏體,增加了室溫組織中的奧氏體含量。(4)高氮奧氏體不銹鋼在變形量小于2%時(shí)候,氮含量的增加能顯著提高奧氏體不銹鋼的屈服強(qiáng)度;當(dāng)變形量超過(guò)5%以后,試樣中可能有形變馬氏體產(chǎn)生,使得氮含量較低的試樣應(yīng)力值顯著增大,而氮含量較高的試樣中,強(qiáng)化仍以加工硬化為主。
[Abstract]:Stainless steel is one of the most common metals in daily life. It is widely used because of its good mechanical properties and excellent corrosion resistance. Nitridation of stainless steel with nitrogen instead of nickel can not only guarantee the properties of stainless steel, but also save resources, so it has been paid more and more attention. The common nitriding technology of stainless steel is mainly liquid phase nitriding and solid phase nitriding. But liquid phase nitriding has some problems such as poor nitriding effect and complicated process. The nitriding time is long and the thickness of nitriding layer is limited during solid phase nitriding. In this study, the nitriding process was improved, and a new nitriding method was put forward. It is mainly made use of the characteristic of coexistence of solid and liquid two phases in the temperature range of the paste zone to hold heat for a certain time so that nitrogen can be dissolved into liquid phase and diffused into austenitic phase, and the nitrogen content in the microstructure at room temperature will be increased. Through experimental and theoretical research, the following conclusion is drawn: during the heat preservation process of the paste zone, the nitrogen content increases gradually with the increase of the holding time, when the nitrogen pressure is 0.1MPa, The nitrogen content increased from 0.17% to 0.23%, while the porosity decreased from 1.86% to 1.37%, and when the nitrogen pressure was 0.4MPa, the nitrogen content increased from 0.29% to 0.37%, and the porosity decreased from 1.41% to 1.066.When the nitrogen pressure was 0.4MPa, the nitrogen content increased from 0.29% to 0.37%. The results show that the gelatinized zone heat preservation process can effectively increase the nitrogen content in steel, and decrease the porosity of ingot at the same time) the change of microstructure with nitrogen content in the heat preservation process of paste zone is explored, which indicates that in the heat preservation process of paste zone, the change of microstructure with nitrogen content is discussed. The continuous dissolution of nitrogen in liquid steel will cause the isothermal transformation of ferrite in the microstructure. Some ferrite react with the liquid phase to form austenite, the other part changes from solid phase transformation to austenite. The mechanism of nitrogen increasing in the paste region is explained: on the one hand, the nitrogen increasing in the paste region promotes the transformation of ferrite to austenite, and the increase of austenite content increases the solubility of nitrogen in the alloy. The increase of nitrogen content leads to the direct transformation of liquid phase to austenite, which increases the austenite content in the room temperature microstructure. The yield strength of austenitic stainless steel can be significantly increased by the increase of nitrogen content when the deformation amount of high nitrogen austenitic stainless steel is less than 2%. When the amount of deformation exceeds 5%, there may be deformed martensite in the sample, which makes the stress value of the sample with lower nitrogen content increase significantly, but the strengthening of the sample with higher nitrogen content is still mainly work hardening.
【學(xué)位授予單位】：昆明理工大學(xué)
【學(xué)位級(jí)別】：碩士
【學(xué)位授予年份】：2017
【分類號(hào)】：TG142.71;TG156.82

【參考文獻(xiàn)】

相關(guān)期刊論文 前10條

1 喬巖欣;王碩;劉彬;鄭玉貴;李花兵;姜周華;;新型高氮鋼的腐蝕和空蝕交互作用研究[J];金屬學(xué)報(bào);2016年02期

2 劉春粟;李鑫;畢洪運(yùn);;冷變形對(duì)節(jié)鎳型奧氏體不銹鋼組織性能的影響[J];材料熱處理學(xué)報(bào);2014年S2期

3 王書(shū)桓;趙定國(guó);;高壓冶金技術(shù)在高氮鋼冶煉中的應(yīng)用[J];太原理工大學(xué)學(xué)報(bào);2014年01期

4 王書(shū)桓;吳彥輝;趙定國(guó);;凝固壓力對(duì)高氮鋼中氮宏觀偏析的影響[J];鑄造技術(shù);2013年07期

5 郎宇平;陳海濤;翁宇慶;屈華鵬;;熱力學(xué)計(jì)算在高氮奧氏體不銹鋼研究中的應(yīng)用[J];材料工程;2013年05期

6 徐國(guó)富;李曉源;時(shí)捷;;熱變形對(duì)高氮奧氏體不銹鋼Mn18Cr18N組織和顯微硬度的影響[J];特殊鋼;2013年02期

7 向紅亮;顧興;;含氮不銹鋼研究概況[J];金屬世界;2013年01期

8 王耘濤;任伊賓;楊柯;張育增;;高溫滲氮工藝對(duì)高氮無(wú)鎳不銹鋼組織及力學(xué)性能的影響[J];金屬熱處理;2012年05期

9 ;High nitrogen nickel-free austenitic stainless steel:A promising coronary stent material[J];Science China(Technological Sciences);2012年02期

10 陳巍;劉燕林;田雨江;宗鐸;魏潔;蘇繼紅;王英;;高氮鋼材料組織及性能研究[J];兵器材料科學(xué)與工程;2010年06期

相關(guān)博士學(xué)位論文 前3條

1 付俊偉;亞快速凝固奧氏體不銹鋼組織形成及演化規(guī)律研究[D];哈爾濱工業(yè)大學(xué);2009年

2 王松濤;高氮奧氏體不銹鋼的力學(xué)行為及氮的作用機(jī)理[D];中國(guó)科學(xué)院研究生院（理化技術(shù)研究所）;2008年

3 李花兵;高氮奧氏體不銹鋼的冶煉理論基礎(chǔ)及其材料性能研究[D];東北大學(xué);2008年

，

本文編號(hào)：1854281