發(fā)布時間：2018-04-17 17:44

  本文選題：環(huán)三磷腈 + 金屬-有機骨架化合物��； 參考：《浙江師范大學(xué)》2016年碩士論文

【摘要】：環(huán)三磷腈及其衍生物是一類很重要的分子,在超分子化學(xué)和材料化學(xué)中得到了廣泛的應(yīng)用。然而,關(guān)于環(huán)三磷腈及其衍生物的MOF材料仍然很少被探索。在本文中,我們設(shè)計并合成了三種新穎環(huán)三磷腈功能化多羧酸配體,分別是六(3,5-二羧基苯氧基)環(huán)三磷腈(H12L)、六(4-羧基苯氧基)環(huán)三磷腈(H6L1)和六(3-羧基苯氧基)環(huán)三磷腈(H6L2)。并使用它們分別與過渡金屬離子、堿土金屬離子和稀土金屬離子反應(yīng),通過溶劑熱法合成了12個金屬-有機骨架化合物,分別是：[Cu3L(H2O)3]·5DMA·4EtOH·2H2O (L= L1) (1)[Cu3L(H2O)3]·5DMF·2MeOH·2H2O (L= L2) (2)[Cd5L(H2O)4]·2(CH3)2NH2·6DMF (L=L) (3)[Mg3L2(H2O)6]·6(Me2NH2)·DMA·H2O (L=L1) (4)[Ca3L(DMF)2](L=L1)(5)[Ba3L(H2O)4(DMF)]·DMF·2H2O (L=L1) (6)[Sm4L2(CH3COO)(H2O)]·(CH3)2NH2·17DMA (L=L1) (7)[Eu4L2(CH3COO)(H2O)]·(CH3)2NH2·17DMA (L=L1) (8)[Gd4L2(CH3COO)(H2O)]·(CH3)2NH2·13DMA (L=L1) (9)[Tb4L2(CH3COO)(H2O)]·(CH3)2NH2·15DMA (L=L1) (10)[Dy4L2(CH3COO)(H2O)]·(CH3)2NH2·17DMA (L=L1) (11)[Ho4L2(CH3COO)(H2O)]·(CH3)2NH2·20DNA (L=L1) (12)對合成的配合物進(jìn)行單晶結(jié)構(gòu)分析和常規(guī)表征,并研究了其中幾個配合物在氣體吸附分離和熒光檢測方面的應(yīng)用。
[Abstract]:Cyclotriphosphazene and its derivatives are very important molecules and have been widely used in supramolecular chemistry and material chemistry.However, MOF materials for cyclotriphosphazene and its derivatives are rarely explored.In this paper, we have designed and synthesized three novel cyclic triphosphazene-functionalized polycarboxylic acid ligands, namely, hexachlorotriphosphazene-5-dicarboxyphenoxy) cyclotriphosphazene (H12LN), hexachloro 4-carboxyphenoxy) cyclotriphosphazene (H6L1) and hexachloro-3-carboxyphenoxy) cyclotriphosphazene (H6L2).Twelve metal-organic skeleton compounds were synthesized by solvothermal reaction with transition metal ions, alkali earth metal ions and rare earth metal ions, respectively.鍒嗗埆鏄，

本文編號：1764632