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溶膠-凝膠法制備銅鋅錫硫材料的研究進(jìn)展

發(fā)布時(shí)間:2018-09-10 13:21
【摘要】:四元硫化物銅鋅錫硫(CZTS)是一種新型薄膜太陽(yáng)電池材料,具有鋅黃錫礦結(jié)構(gòu),呈p型導(dǎo)電性,帶隙約為1.5eV,光學(xué)吸收系數(shù)高于104cm-1,這些特性與太陽(yáng)光譜相匹配;谏鲜鲈,CZTS薄膜是一種有望能低成本、可規(guī)模化開發(fā)利用的新型薄膜太陽(yáng)電池材料。簡(jiǎn)要闡述了CZTS性質(zhì)及其薄膜太陽(yáng)能電池的器件結(jié)構(gòu),詳細(xì)介紹了溶膠-凝膠方法制備CZTS薄膜及其相應(yīng)器件效率的研究進(jìn)展。最后,總結(jié)了此方法制備CZTS薄膜及其相關(guān)電池性能難以突破的關(guān)鍵技術(shù)問題,并提出了有效的改進(jìn)措施,對(duì)CZTS薄膜太陽(yáng)電池未來的研究進(jìn)行了展望。
[Abstract]:Quaternary sulfide-copper-zinc-tin sulfur (CZTS) is a new thin film solar cell material with a zinc-yellow tin structure, a p-type conductivity, a band gap of about 1.5 EV and an optical absorption coefficient of more than 104 cm ~ (-1). These characteristics are consistent with the solar spectrum. For these reasons, CZTS thin film is a new kind of thin film solar cell material which is expected to be low cost and can be developed on a large scale. The properties of CZTS and the device structure of thin film solar cells are briefly described. The research progress in the preparation of CZTS thin films by sol-gel method and their corresponding device efficiency are introduced in detail. Finally, the key technical problems of preparing CZTS thin film and its related battery performance are summarized, and the effective improvement measures are put forward, and the future research of CZTS thin film solar cell is prospected.


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