国产伦乱,一曲二曲欧美日韩,AV在线不卡免费在线不卡免费,搞91AV视频

當(dāng)前位置:主頁(yè) > 科技論文 > 材料論文 >

剛性二苯乙烯衍生物的自組裝單層膜的光響應(yīng)性

發(fā)布時(shí)間:2018-08-07 07:18
【摘要】:刺激響應(yīng)性表面可以在外界刺激下改變表面宏觀性質(zhì)(比如潤(rùn)濕性、粘附性、粗糙度、生物相容性)。不同類型的外界刺激(包括熱、光、pH、電和化學(xué)添加劑等)可以被應(yīng)用到這些表面上。這些刺激中,光可以提供一個(gè)清潔、非侵入的、可調(diào)節(jié)的能量輸入,并且具有光化學(xué)反應(yīng)的響應(yīng)時(shí)間短的特點(diǎn),從而引起越來(lái)越多的關(guān)注。控制潤(rùn)濕性可以通過(guò)對(duì)表面進(jìn)行化學(xué)修飾從而改變液體對(duì)表面的親和力。光控分子開(kāi)關(guān)對(duì)制備潤(rùn)濕性可控的表面提供了一個(gè)新的途徑。關(guān)于光控分子開(kāi)關(guān)修飾的表面的潤(rùn)濕性研究中,提出了很多增大偶氮苯/螺吡喃不同構(gòu)型修飾的表面潤(rùn)濕性差別的方法,比如混合膜、增加表面粗糙度以及使用聚合物修飾的表面。但是,控制平滑表面上的光響應(yīng)自組裝單層膜的潤(rùn)濕性仍然是個(gè)挑戰(zhàn)。 剛性二苯乙烯是一個(gè)光響應(yīng)基團(tuán),具有熱穩(wěn)定性好、異構(gòu)體構(gòu)型差異大、平面性好等特點(diǎn)。基于剛性二苯乙烯的光響應(yīng)性我們?cè)O(shè)計(jì)合成了分子S5,順式和反式S5自組裝單層膜水接觸角分別為67.8°和66.3°,差別很小。為了增大順式和反式剛性二苯乙烯衍生物自組裝單層膜潤(rùn)濕性的差別,在S5的基礎(chǔ)上接上脲基乙酸,合成分子S7。順式和反式S7自組裝單層膜水接觸角分別為63.8°和56.4°,差值為7.4°,我們得到了在不同構(gòu)型下潤(rùn)濕性不同的自組裝單層膜。其中,順式S7自組裝單層膜經(jīng)光照后水接觸角無(wú)明顯變化,可能是因?yàn)镾7沒(méi)有足夠大的空間發(fā)生異構(gòu)。為了減小空間阻礙,,制備了順式S7/正丁硫醇混合自組裝單層膜,水接觸角為70.8°。經(jīng)392nm光照后,水接觸角減小到60.4°;再經(jīng)過(guò)352nm光照后,水接觸角與352nm光照前相比無(wú)明顯變化,因此,順式S7/正丁硫醇混合自組裝單層膜是一個(gè)具有單向光響應(yīng)性的薄膜。
[Abstract]:Stimulative responsive surfaces can change the macroscopic properties of surfaces under external stimulation (e. G. Wettability, adhesion, roughness, biocompatibility). Different types of external stimuli (including heat, light pH, electrical and chemical additives, etc.) can be applied to these surfaces. Among these stimuli, light can provide a clean, non-invasive, adjustable energy input, and has the characteristics of short response time of photochemical reaction, which has attracted more and more attention. Controlling wettability can change the affinity of liquid to the surface by modifying the surface chemically. Optically controlled molecular switches provide a new way to prepare wettability controllable surfaces. In the study of the wettability of the surface modified by optically controlled molecular switches, many methods have been proposed to increase the wettability of the surface modified by azobenzene / spiropyran, such as the mixed film. Increase surface roughness and use polymer modified surfaces. However, controlling the wettability of self-assembled monolayers on smooth surfaces remains a challenge. Rigid stilbene is a photo-responsive group with good thermal stability, great difference in the configuration of isomers and good planarity. Based on the photoresponse of rigid stilbene, the water contact angles of S5, cis-and trans-S5 self-assembled monolayers were 67.8 擄and 66.3 擄, respectively. In order to increase the wettability of self-assembled monolayers of cis and trans rigid stilbene derivatives, the synthesis molecule S7 was synthesized by adding urea acetic acid on the basis of S5. The water contact angles of cis-and trans-S7 self-assembled monolayers are 63.8 擄and 56.4 擄, respectively, and the difference is 7.4 擄. We have obtained self-assembled monolayers with different wettability under different configurations. The water contact angle of Cis-S7 self-assembled monolayer film does not change obviously after illumination, which may be due to the isomerism of S7. In order to reduce the space barrier, a cis S7 / n-butyl mercaptan mixed self-assembled monolayer was prepared with a water contact angle of 70.8 擄. After 392nm illumination, the water contact angle decreased to 60.4 擄, and after 352nm illumination, the water contact angle did not change significantly compared with that before 352nm illumination. Therefore, the cis-S _ 7 / n-butyl mercaptan mixed self-assembled monolayer was a unidirectional photo-responsive film.
【學(xué)位授予單位】:吉林大學(xué)
【學(xué)位級(jí)別】:碩士
【學(xué)位授予年份】:2015
【分類號(hào)】:O625.12;TB383.2

【參考文獻(xiàn)】

相關(guān)期刊論文 前1條

1 沈家驄,張希;超分子科學(xué)──21世紀(jì)新概念與高技術(shù)的一個(gè)重要源頭[J];科技導(dǎo)報(bào);1994年10期

相關(guān)博士學(xué)位論文 前1條

1 徐磊華;硅烷類自組裝復(fù)合層的制備及摩擦學(xué)性能研究[D];中國(guó)礦業(yè)大學(xué);2011年



本文編號(hào):2169278

資料下載
論文發(fā)表

本文鏈接:http://lk138.cn/kejilunwen/cailiaohuaxuelunwen/2169278.html


Copyright(c)文論論文網(wǎng)All Rights Reserved | 網(wǎng)站地圖 |

版權(quán)申明:資料由用戶4a4e3***提供,本站僅收錄摘要或目錄,作者需要?jiǎng)h除請(qǐng)E-mail郵箱bigeng88@qq.com
男女日逼的视频免费看| 欧美 偷拍自拍| 欧美日韩国产精品久久婷婷小说| 超碰性爱| 河南少妇久久| 熟女视频夜午91| 日韩和的一二区| 黄色版久久久| 日本啪不卡| 99久久婷婷国产一区二区推荐| 国产高清无码不卡在线观看二区| 国产亚洲综合性久久久| 日韩国产欧美情色| 亚洲中文天堂在线| 国产 在线 欧美 另类| 大黑屌骚逼综合网| 丝袜亚洲美腿在线中文字幕| 99re手机免费在线视频| 97精品人妻在线视频区| 欧洲美洲不卡av| 一级A级高清无码网站免| 麻豆网页视频| 亚洲1区第2区第3区第4| 欧美精品色情一区二区| 青青草机国产精品| 永嘉县| 午夜扣水伦理视频| 麻豆网站在线免费观看| 亚洲精A网址| 国产精品无码久久AV不卡| 污视频线观看三区| 草草影院一区二区| 午夜精品一区二区三区,…| 日韩欧美精品区第一页| www.99热在线视频| 日韩av专区伦理| 久久久久,香港黄色片| 人人摸超碰免费麻豆| 美國人xxxxxxxx| av在线综合日韩| 伊人超碰在线不卡|